| Round | Overall | Player |
|---|---|---|
| 1 | 2nd | 1B Albert Pujols LAA |
| 2 | 23rd | SS Hanley Ramirez LAD |
| 3 | 26th | C Carlos Santana Cle |
| 4 | 47th | SP Tim Lincecum SF |
| 5 | 50th | SP Dan Haren Was |
| 6 | 71st | SP Madison Bumgarner SF |
| 7 | 74th | DH Lance Berkman Tex |
| 8 | 95th | OF Andre Ethier LAD |
| 9 | 98th | SP Mat Latos Cin |
| 10 | 119th | 2B Dustin Ackley Sea |
| 11 | 122nd | SP Matt Garza ChN |
| 12 | 143rd | SS Erick Aybar LAA |
| 13 | 146th | OF Jayson Werth Was |
| 14 | 167th | OF Bryce Harper Was |
| 15 | 170th | OF Nick Markakis Bal |
| 16 | 191st | SP Cory Luebke SD |
| 17 | 194th | SP Wandy Rodriguez Pit |
| 18 | 215th | SP Jonathon Niese NYN |
| 19 | 218th | SP Tim Stauffer SD |
| 20 | 239th | 1B Matt Gamel Mil |
| 21 | 242nd | OF Jason Bay NYN |
| 22 | 263rd | OF Lucas Duda NYN |
| 23 | 266th | SP Edison Volquez SD |
| 24 | 287th | SP Bud Norris Hou |
| 25 | 290th | OF Alfonso Soriano ChN |
| 26 | 311th | 2B Omar Infante Det |
| 27 | 314th | SS Willie Bloomquist Ari |
| 28 | 335th | C Wilin Rosario Col |
| 29 | 338th | 3B Placido Polanco Mia |