| Round | Overall | Player |
|---|---|---|
| 1 | 2nd | 1B Albert Pujols LAA |
| 2 | 23rd | SP Roy Halladay Phi |
| 3 | 26th | SP C.C. Sabathia NYA |
| 4 | 47th | SP Zack Greinke LAD |
| 5 | 50th | SS Starlin Castro ChN |
| 6 | 71st | RP Mariano Rivera NYA |
| 7 | 74th | 3B Aramis Ramirez Mil |
| 8 | 95th | OF Melky Cabrera Tor |
| 9 | 98th | SP Ian Kennedy Ari |
| 10 | 119th | RP J.J. Putz Ari |
| 11 | 122nd | C Yadier Molina StL |
| 12 | 143rd | 2B Danny Espinosa Was |
| 13 | 146th | SP Brandon McCarthy Ari |
| 14 | 167th | OF Austin Jackson Det |
| 15 | 170th | RP Drew Storen Was |
| 16 | 191st | OF Brennan Boesch Det |
| 17 | 194th | OF Lucas Duda NYN |
| 18 | 215th | 3B Danny Valencia Min |
| 19 | 218th | 1B Carlos Lee Mia |
| 20 | 239th | SP Mike Minor Atl |
| 21 | 242nd | SS Ian Desmond Was |
| 22 | 263rd | C Russell Martin NYA |
| 23 | 266th | OF Dayan Viciedo ChA |
| 24 | 287th | 1B James Loney TB |
| 25 | 290th | OF Alejandro De Aza ChA |
| 26 | 311th | OF Denard Span Was |
| 27 | 314th | SP Drew Pomeranz Col |
| 28 | 335th | 2B Omar Infante Det |
| 29 | 338th | OF Mike Trout LAA |