| Round | Overall | Player |
|---|---|---|
| 1 | 4th | OF Matt Kemp LAD |
| 2 | 21st | SP Clayton Kershaw LAD |
| 3 | 28th | OF Jason Heyward Atl |
| 4 | 45th | SS Starlin Castro ChN |
| 5 | 52nd | RP Craig Kimbrel Atl |
| 6 | 69th | 1B Freddie Freeman Atl |
| 7 | 76th | SP R.A. Dickey Tor |
| 8 | 93rd | SP Max Scherzer Det |
| 9 | 100th | 3B David Freese LAA |
| 10 | 117th | OF Andre Ethier LAD |
| 11 | 124th | 2B Howie Kendrick LAA |
| 12 | 141st | OF Mark Trumbo Ari |
| 13 | 148th | SP Jeff Samardzija ChN |
| 14 | 165th | SP Anibal Sanchez Det |
| 15 | 172nd | 1B Mike Napoli Bos |
| 16 | 189th | SP Tom Milone Oak |
| 17 | 196th | RP John Axford Cle |
| 18 | 213th | OF Shane Victorino Bos |
| 19 | 220th | C A.J. Pierzynski Tex |
| 20 | 237th | C Robert Brantly Mia |
| 21 | 244th | SS Sean Rodriguez TB |
| 22 | 261st | 3B Wilson Betemit Bal |
| 23 | 268th | SP Marco Estrada Mil |
| 24 | 285th | 2B Mark Ellis LAD |
| 25 | 292nd | SP Chad Billingsley LAD |
| 26 | 309th | SP Tyler Skaggs Ari |
| 27 | 316th | OF Jeff Francoeur KC |
| 28 | 333rd | 3B Mike Olt ChN |
| 29 | 340th | SP John Danks ChA |