| Round | Overall | Player |
|---|---|---|
| 1 | 12th | 1B Anthony Rizzo ChN |
| 2 | 13th | SP Felix Hernandez Sea |
| 3 | 36th | SP Max Scherzer Was |
| 4 | 37th | 3B Adrian Beltre Tex |
| 5 | 60th | SP Adam Wainwright StL |
| 6 | 61st | SP Cole Hamels Tex |
| 7 | 84th | OF Jason Heyward StL |
| 8 | 85th | SP Sonny Gray Oak |
| 9 | 108th | OF Shin-Soo Choo Tex |
| 10 | 109th | SP Gio Gonzalez Was |
| 11 | 132nd | 2B Kolten Wong StL |
| 12 | 133rd | OF Jayson Werth Was |
| 13 | 156th | DH Chris Carter Hou |
| 14 | 157th | RP Mark Melancon Pit |
| 15 | 180th | C Salvador Perez KC |
| 16 | 181st | 1B Matt Adams StL |
| 17 | 204th | SS Danny Santana Min |
| 18 | 205th | RP Kenley Jansen LAD |
| 19 | 228th | SP Homer Bailey Cin |
| 20 | 229th | OF Curtis Granderson NYN |
| 21 | 252nd | OF Desmond Jennings TB |
| 22 | 253rd | SP Carlos Martinez StL |
| 23 | 276th | C Alex Avila Det |
| 24 | 277th | 2B Rougned Odor Tex |
| 25 | 300th | SS Brad Miller Sea |
| 26 | 301st | OF Byron Buxton Min |
| 27 | 324th | 1B Yonder Alonso SD |
| 28 | 325th | RP Sean Doolittle Oak |
| 29 | 348th | SP Mark Buehrle Tor |